Geology of the Curone and Staffora Valleys (NW Italy): field constraints for the Late Cretaceous – Pliocene tectono-stratigraphic evolution of Northern Apennines

ABSTRACT In the northwestern part of Northern Apennines, between Curone and Staffora Valleys, the tectonic superposition between the External Ligurian Units (i.e. the ophiolitic-bearing chaotic complex of the Groppallo Unit and the non-ophiolitic Cassio Unit), the Middle Eocene – Miocene wedge-top basin Epiligurian Units succession, and the Late Messinian – Pliocene Po Plain succession, records the multistage tectono-stratigraphic evolution from subduction to continental collision. Our geological map, at the 1:20,000 scale, allows us to define 6 main tectonic stages on the basis of (i) the crosscutting relationships between main faults and local to regional stratigraphic unconformities and (ii) the differentiation among different types of chaotic rock unit (olistostromes and broken formations) deposited since Late Cretaceous to late Messinian. This approach provides a new understanding on the tectono-stratigraphic evolution of this sector, and its meaning in the evolution of the northwestern part of Northern Apennines.


Introduction
In the hanging wall of the Apenninic thrust front, the northwestern part of Northern Apennines belt (between Voghera and Piacenza) is characterized by complex structural relationships among discontinuous remnants of ophiolite-bearing chaotic units (e.g. Boccaletti & Coli, 1982) of Late Cretaceous age (i.e. Western External Ligurian Unit, see Marroni & Pandolfi, 2007), non-ophiolitic External Ligurian Units (e.g. Eastern External Ligurian Unit, see Marroni & Pandolfi, 2007), and the overlaying wedge-top basin Epiligurian Units (Figure 1). Although this sector is covered by different editions of the Geological Map of Italy (e.g. Bellinzona, Boni, Braga, & Marchetti, 1971;Boni, 1969;Vercesi et al., 2005Vercesi et al., , 2015, the understanding of the tectono-stratigraphic relationships between these different units is complicated by poor rock exposures and lack of continuous outcrops. A new detailed geological mapping, focused on (i) the crosscutting relationships between main faults and local to regional stratigraphic unconformities and (ii) the differentiation among different types of chaotic rock unit (i.e. olistrostromes and broken formations) of various age, provides further specific data covering the partial lack of geological information, allowing a new understanding on the tectono-stratigraphic evolution of this sector and its meaning in the evolution of the northwestern part of Northern Apennines.
On the basis of a new geological mapping at the 1:5000 scale, detailed structural and stratigraphic observations, and targeted collection of biostratigraphic data, we present the 'Geological map of the Curone and Staffora Valleys (Northern Apennines, Italy)' (see Main Map) at the 1:20,000 scale. This Geological Map represents the northern prolongation of the 'Geological Map of the Villalvernia -Varzi Line between Scrivia and Curone valleys (NW Italy)' by Festa, Fioraso, Bissacca, and Petrizzo (2015).

Methods
The geological map was produced from about four years (2014)(2015)(2016)(2017) of fieldwork at the 1:5000 scale and accompanying detailed structural analyses and stratigraphic observations. The definition of the structural setting of the sector was defined through the mapping of the crosscutting relationships between main faults and local to regional stratigraphic unconformities that are documented in the attached geological map at the 1:20,000 scale (see Main Map), using the topographic maps 'CTR -Carta Tecnica Regionale' of Regione Piemonte and Regione Lombardia. The dis-tinction among different types of chaotic rock units (i.e. olistostromes and broken formations) followed specific criteria defined in literature (e.g. Bettelli & Panini, 1989;Bettelli, Conti, Panini, & Vannucchi, 2006;Dilek, Festa, Ogawa, & Pini, 2012;Festa, Dilek, Codegone, Cavagna, & Pini, 2013;Festa, Ogata, Pini, Dilek, & Alonso, 2016;Pini, 1999). The geological map was edited using the methodological cartographic and representative criteria from the CARG Project (Project of Geological Cartography) of Italy, at the 1:50,000 scale (see Pasquaré, Abbate, Bosi, et al., 1992;.

External Ligurian Units
The stratigraphic succession (Chronostratigraphic Scheme in Main Map) of the Cassio Unit shows a complete transition from the 'Basal Complex' (Scabiazza Sandstone and Argille Varicolori) to the late Maastrichtian -Late Palocene Viano Clays. The Scabiazza Sandstone (SCB in the Main Map, late Albian-Santonian) consists of a strongly disrupted chaotic succession (broken formation sensu Hsü, 1968) with bed fragments of whitish micaceous sandstones, embedded into a pelitic-to argillaceous matrix (Figure 2(a,b)).
The analysis of calcareous nannofossils shows mixing of late Albian, Aptian-Albian, Early Cretaceous and Early Jurassic taxa, and few taxa younger than Coniacian. The Argille Varicolori (AVV in the Main Map, Varicolored scaly clays; Santonian -Campanian; Figure 2(c)) also represent a highly disrupted broken formation with blocks (limestones, sandstones, and manganiferous siltstones), deriving from stratal disruption of the primary lithostratigraphic unit, embedded in a varicolored (gray, red, and purple) clays and shales matrix. Tens of meters thick body of Salti del Diavolo Conglomerate (AVV 1 in the Main Map, Figure 2(d)), with clasts consisting of prevailing carbonate rocks and minor micaschist, gneiss, quartzite, granulite, pinkish granite and diorite, are interbedded within the Argille Varicolori. The latter are overlain by the late Campanian Monte Cassio Flysch (MCS in the Main Map, Figure 2(e)), which consists of alternating beds of clayey marls and carbonate-rich calcareousmarly turbidites, dm to m thick. The Viano Clay (AVI in the Main Map, late Maastrichtian -Late Paleocene), consisting of alternating layers of claystones and less abundant limestones in dm thick beds, closes upward the stratigraphic succession of the Cassio Unit.
The Groppallo Unit consists of a chaotic complex with a block-in-matrix fabric (the Pietra Parcellara Complex -CPP in the Main Map), up to 150 m (or more) in thickness, in which heterogeneous blocks, up to hundreds of m in size (Figure 2(f)), are randomly distributed in a matrix of coarse-grained ophiolitic sandstones ( Figure 2(g,h)) and polymictic argillaceous breccias. Huge blocks (olistoliths) are represented by mantle ultramafic rocks (i.e. spinel-lherzolites) locally intruded by small gabbro bodies, while clasts consist of lherzolites, gabbros, bed fragments of Calpionella Limestone and Palombini Shale, minor basalts, cherts (i.e. Radiolarites) and granitoids. It is worth noting that, although the nature of blocks and clasts of this Unit closely resemble that one of the Casanova Complex Auct. (sensu Bertotti, Elter, Marroni, Meccheri, & Santi, 1986;Elter, Marroni, Molli, & Pandolfi, 1991;Marroni et al., 2001) rather than the classical one described for the Pietra Parcellara Complex (see, e.g. Marroni et al., 2010;Vercesi et al., 2015), we prefer to maintain this last formational name because its structural position is well consistent with that of the Gropallo Unit described in the Northern Apennines (e.g. Vercesi et al., 2005;. Analyses of calcareous nannofossils show an early Campanian age (CC18 zone of Sissingh, 1977) for the uppermost part of this chaotic complex.

Epiligurian Succession
The Epiligurian Succession starts with the Baiso Argillaceous Breccias (BAI in the Main Map, Lutetian -Bartonian) (Figure 3(a)), which consist of a lenticular and laterally discontinuous mass-transport chaotic deposit (olistostrome) sourced from the downslope dismemberment of the 'Basal Complex' and Monte Cassio Flysch. They pass upward (and local laterally) to hemipelagic clays and marls of the Monte Piano Marls (MMP in the Main Map, Lutetian -Priabonian) (Figure 3(b,c)), which are overlain through an erosive unconformity surface (Figure 3(b)) by turbidites of the Ranzano Formation. The latter, which is locally deposited directly above the External Ligurian Succession, is subdivided in three superimposed members (Pizzo d'Oca Member -RAN 1 in the Main Mapof late Priabonian age, Val Pessola Member -RAN 2of late Priabonianearly Rupelian age, and Varano de' Melegari Member -RAN 3of middlelate Rupelian age; Figure 3(b), (d), and (e)), which differ for the stratigraphic position and petrographic composition of lithic fragments (see, e.g. Cibin, Di Giulio, & Martelli, 2003;Martelli, Cibin, Di Giulio, & Catanzariti, 1998;Mutti et al., 1995). The succession continued, through an unconformity surface, with the slope finegrained hemipelagic deposits of the Antognola Formation (ANT and ANT 1a in the Main Map, late Rupelian -Aquitanian), which includes olistostromal lenticular bodies, up to 60 m thick, of the Val  Contignaco Formation (CTG in the Main Map, late Aquitanian -Burdigalian; see Figure 3(g)) drape both the Ranzano Formation and Antognola Formation. The stratigraphic contact with Ranzano Formation (Colletta sector) corresponds to an angular unconformity, which passes laterally to a correlative conformity (Case Cucchi sector) where the Contignaco Formation overlies the Antognola Formation. In the latter sector, locally, the lower part of the Contignaco Formation is characterized by slumping structures. The Monte Lisone Chaotic Complex (CML in the Main Map, Late Burdigalian -Langhian?), which represents another mass-transport chaotic deposit (olistostrome), rests unconformably on both the uppermost part of the External Ligurian Succession and the Antognola Formation. It differs from the above described olistrostromes on the basis of the nature of blocks, consisting of only disrupted bed fragments of Helminthoides Flysch, and to the South of the studied sector it is overlain by the Monte Vallassa Sandstone (see Festa, Fioraso, et al., 2015 for major details). The Epiligurian Succession continues through a regional unconformity with the shallow and coarse shelf deposits of the Monte Vallassa Sandstone (AMV in the Main Map, Gelati & Vercesi, 1994) of the Bismantova Group, Langhian -Serravallian in age (Figure 3(h)). In the northern sector of the studied area, late Messinian

Tectonic setting
The tectonic setting is characterized by the ENE-trending of tectonic structures (thrusts, strike-slip faults, and regional scale folds), which are rotated to WNW-trending to the West of Curone Valley, being displaced by WNW-to NW-striking strike-slip faults (see Main Map and related Structural scheme).
In the north-central part of the studied sector, the Barca-Sala Thrust (BST hereafter), ENE-striking and SSE dipping, superposes the Cassio Unit and Epiligurian Succession onto a composite tectonic unit, characterized by the tectonic relationships among the Cassio Unit, the Middle Eocene to Burdigalian part of the Epiligurian Succession, and the Groppallo Unit (see cross sections 3 and 4 in Main Map). The BST, which is splitted into two main sub-parallel surfaces bounding an elongated slice of Argille Varicolori, shows a gradual decrease of offset toward WSW where it is truncated by a NW-striking fault located along the Curone Valley. The hanging wall of the BST is deformed by E-to ENE-trending open folds, which involve the Epiligurian Succession up to the Monte Vallassa Sandstone. Here, the Cassio Unit depicts a roughly SE-dipping monocline, with local open folds with NE-to ENE-striking fold axis. Two main fault systems (ENE-and N-directed) dissect the hanging wall succession. The ENE-striking faults mainly define a deformation zone (Momperone -Vignola Deformation Zone -MVDZ hereafter), several km long and hundreds of m wide, formed by the interlacing of E-and ENE-striking fault segments. In detail, the latters show transpressive left-and right-lateral movements, respectively (Figure 4(a)). In the Colletta sector, the MVDZ is unconformable sealed by the Contignaco Formation and, to the south (Vignola sector), by the Monte Vallassa Sandstone (see cross section 3 in Main Map, Figure 4 (Figure 4(a)).
In the footwall of the BST, the Groppallo Unit defines a tectonic window overthrust by the Cassio Unit along a thrust folded by a NW-striking, open to gentle anticline, with SE-fold axis plunge (see Main Map). The thrust dips to NE and SW in the northeastern and southwestern sides of the tectonic window, respectively, superposing the Scabiazza Sandstone (northestern side), the Monte Cassio Flysch and the Scabiazza Sandstone (southwestern side) onto the Pietra Parcellara Complex (see cross section 2 in Main Map). Along the northeastern side of the tectonic window, the Scabiazza Sandstone is locally involved by thrust splays and imbricated with the Pietra Parcellara Complex, forming lenticular tectonic slices, hundreds of m in length. To ENE, the footwall of the BST is characterized by a hundreds of meters wide and 5 km long deformation zone (San Desiderio Deformation Zone -SDDZ hereafter), which is about WNW-ESE and ENE-WSW oriented to the West and East sectors of the Staffora Valley, respectively (Figure 4(c)). Mesoscale structural associations (S-C shears; Figure  4 Figure 4(c)). Far from faults bounding the SDDZ, the Argille Varicolori preserve an earlier layer-parallel extensional block-in-matrix fabric, which is deformed by rootless and transposed folds (Figure 4 (e,f)). The latters are characterized by curviplanar axial surfaces, with fold axes displaying a broad girdle with WNW-and ESE-oriented maxima (Figure 4(a,e)), and asymmetrical boudinaged limbs by R and C' shears along NE-SW cross sections, commonly displaced by localized shear zones. The tectonic setting above described is cut by two main fault systems, NW-and N-striking. The former corresponds to pluri-km long faults, which cut with left-lateral movements, reactivated by right-lateral ones as shown by fault striations (slickenlines) on fault surfaces (Figure 4(a)) and S-C shears, both the BST and the SDDZ (see Main Map). From East to West of the NW-striking fault of the Curone Valley, the main fold axes, bedding surfaces, and stratigraphic boundaries are gradually rotated from ENE-WSW to WNW-ESE directions and cut by NE-striking faults to the West of that Valley (see Main Map).
The N-striking fault system shows best exposures only in the northeaster sector of the studied area (East of Mt. Treno), representing the southern prolongation of the Pliocene Schizzola Valley Fault of Perotti and Vercesi (1991) and Vercesi et al. (2015). The latter defines a hundreds of meters wide deformation zone, with left-lateral kinematics (e.g. Vercesi et al., 2015), bounded by interlaced subvertical faults with anastomosed geometry.

Conclusions
The crosscutting relationships between mapped faults and stratigraphic unconformities, and the distinction of different types of chaotic rock unit, allow describing a detailed tectono-stratigraphic evolution of this sector of the Northern Apennines. Six main tectonic stages have been defined from Late Cretaceous to Pliocene ( Figure 5(a,b)).
. Late Cretaceous -Early Eocene: this tectonic stage preserves the record of both gravitational (i.e. olistostrome) and tectonic-induced (i.e. broken formation) deformation related to the evolution at shallow structural levels of the External Ligurian wedge during the subduction stage. The random distribution of polymictic blocks within the matrix of the Pietra Parcellara Complex (Groppallo Unit) is consistent with mass-transport processes occurred at the wedge front during Campanian time ( Figure  5(b), Eoalpine Phase of Elter et al., 1966; see also, Bertotti et al., 1986;. On the contrary, far from the main faults of the SDDZ, the orientation and distribution of fold axes (with WNW-and ESE-oriented maxima) within the Argille Varicolori is consistent with the tectonic deformation related to NE-SW to NNE-SSW shortening directions, which are commonly attributed (e.g. Cerrina Feroni, Ottria, Martinelli, Levi, Ellero, Ottria, & Pandolfi, 2006) to the Paleocene -Early Eocene European verging overthrust ( Figure 5(b)) of the Helminthoides Flysch nappe onto the 'Basal Complex'. The characteristics of mesoscale deformation within the Argille Varicolori (see 'Tectonic setting') well agree with deformation occurred in the frontal and shallower levels of the External Ligurian wedge, affecting unconsolidated sediments in the latest stages of accretion (e.g. Bettelli & Vannucchi, 2003;Pini, 1999). Although the time for tectonic superposition of the Cassio Unit onto the Groppallo Unit is difficult to constrain because of the lack of a detailed stratigraphic marker, the lack of involvement of Epiligurian Succession suggests it occurred earlier than Middle Eocene time ( Figure 5(a,b)). Regarding the Cassio Unit, it is worth noting that the age of the Scabiazza Sandstone (late Albian -Santonian) is similar to that one observed in the Media Val Taro Unit (see, Vescovi et al., 2002; see also Ostia Sandstone of Vescovi et al., 1999) and in the Cabella Ligure sector (see, Marroni, Ottria, & Pandolfi, 2015), and younger than that one commonly described for the classical Cassio Unit (i.e. Cenomanian -Turonian). Although additional investigations are needed, these data suggest the deposition of this Formation in an outer sector of the Cassio basin (with respect to the West-verging 'Alpine' accretionary wedge), providing new constraints for a more detailed reconstruction of the internal physiography of the depositional environment of the External Ligurian Succession. . Middle Eocene (Lutetian -Bartonian): the wide occurrence of the Baiso Argillaceous Breccias along the SDDZ, ENE-to WNW-oriented, and their increase in thickness away from it, suggest that this deformation zone was active at least since Middle Eocene ( Figure 5(a,b)), favoring mass-transport processes triggered by the tectonic uplift of the 'Basal Complex' and Monte Cassio Flysch. Unfortunately, a detailed description of Middle Eocene kinematics of the SDDZ is hampered by late Messinian -Early Pliocene right-lateral reactivations of main faults (see below 'Late Messinian -Early Pliocene' stage). This mass-transport event marks an important stage of the regional scale instability of the External Ligurian wedge (e.g. Bettelli & Panini, 1989), which can be related to the early stage of continental collision (Mesoalpine stage or Ligurian Phase, e.g. Cerrina Feroni, Ottria, & Ellero, 2004;Elter, 1975;Marroni et al., 2010;Mutti et al., 1995). The uppermost temporal constrain to this tectonic stage is represented by the unconformable deposition of the Ranzano Formation (Late Eocene -Early Oligocene) onto both the Baiso Argillaceous Breccias and External Ligurian Succession ( Figure 5  (a,b)). . Late Priabonian -Rupelian: the NE-and N-striking normal faults, which displace the lower portion of the Epiligurian Succession, controlled the physiography of Late Eocene -Early Oligocene depositional basin as suggested by both the E-W change in thickness of the Val Pessola Mb. and Varano de' Melegari Mb. of the Ranzano Formation (see cross section 1 in Main Map, Figure 5(a)). At the regional scale, this stage is close associated with faulting along the Villalvernia -Varzi Line, which controlled the depositional settings of both the Tertiary Piedmont Basin and Epiligurian Succession (e.g. Di Biase, Marroni, & Pandolfi, 1997;Di Giulio & Galbiati, 1995;Felletti, 2002;Festa, Fioraso, et al., 2015;Marroni et al., 2002;Mutti et al., 1995), and corresponds to the Ligurian phase II of Mutti et al. (1995) and Faulting stage A of Piana (2000) and Festa et al. (2005, Festa, Fioraso, et al. (2015), which are related to the opening of the Balearic Sea. The deposition of the Antognola Formation (late Rupelian -Aquitanian), which unconformably overlains different terms of the Ranzano Formation and External Ligurian Succession, provides the temporal constrain for this tectonic stage ( Figure 5(a,b)). . Chattian -Early Miocene: the former extensional regime was inverted to a compressional one that accompanied the deposition of the Antognola Formation. This stage is mostly recorded along the MVDZ, developed by the interlacing of ENE-striking transpressive right-lateral faults and E-striking transpressive left-lateral ones, and the widespread occurrence of olistostromes of the Val Tiepido -Canossa Argillaceous Breccias, which sourced from denudation of uplifted External Ligurian Succession and the lower part of Epiligurian Succession. In the southwestern sector of the study area, submarine structural highs formed during the Middle Eocene -Rupelian stage were sealed by the unconformable deposition of the Contignaco Formation (Colletta sector; see cross section 3, Figure 5(a,b)). Toward east (e.g. Case Cucchi sector), the occurrence of slumping in the lower part of the Contignaco Formation marks the paleo-scarp connecting the structural highs with a seafloor basinal low, where the unconformity surface at the base of the Contignaco Formation passes gradually to a correlative conformity. A second pulse of gravitational instability occurred in the Burdigalian -Langhian(?) as suggested by the mass-transport emplacement of the Monte Lisone Chaotic Complex. This tectonic stage was definitively sealed by the Monte Vallassa Sandstone, which unconformably overlain faults associated with the MVDZ (Figure 5(a,b)). At the regional scale, this stage is related to the migration toward NE of the Apenninic thrust front (Ligurian Phase III of Mutti et al., 1995;Faulting Stage B of Festa et al., 2005Piana, 2000; see also Piazza et al., 2016). . Late Serravallian -Tortonian(?): The NNW-verging migration of BST, ENE-striking, and the deformation of the Epiligurian Succession with ENE-directed fold axis, well agree with this tectonic stage. The left-lateral NW-striking faults, which displace the lateral continuity of the BST, probably worked as transfer faults ( Figure 5(a,b)) as documented to the south of the study area for the left-lateral Sarizzola Fault Zone, NW-striking, which cuts the Villalvernia -Varzi Fault Zone (see Festa, Fioraso, et al., 2015). At the regional scale, this tectonic stage is related to the northwestward propagation of Apenninic thrust system (e.g. Festa et al., 2005;Mosca et al., 2010;Piana, 2000), during which left-lateral NW-faults represented transfer faults (Costa, 2003). Although only minor evidences are preserved in the mapped area, the uppermost temporal constrain to this tectonic stage is represented by the unconformity at the base of the late Messinian Valle Versa Chaotic Complex immediately to the south ( Figure 5(b); e.g. Festa, Fioraso, et al., 2015 and reference therein. . Late Messinian -Early Pliocene: tectonic deformation triggered the mass-transport emplacement of the Valle Versa Chaotic Complex. NW-striking transtensional faults cut both the SDDZ and the BST ( Figure 5(a,b)). At the northern boundary of the SDDZ, this caused the juxtaposition of the Argille Varicolori to the late Messinian -Early Pliocene succession, while across the Curone Valley it separates sectors characterized by a gradual reorientation of both the late Priabonian -Rupelian faults (from N-to NE-striking; Figure 5(a)) and the main fold axes (from ENE-to NW-striking; Figure 5(a)). This reorientation suggests a refolding of earliest main tectonic features, during which the NW-striking fault of the Curone Valley acted as transfer fault, accommodating part of this deformation ( Figure 5(a)). To the West of the Curone Valley, the displacement of fold axial plane along NE-striking faults also suggests the reactivation of those faults, which controlled the deposition of the Ranzano Formation during the late Priabonian -Rupelian stage. At the regional scale, this stage is related to the N-S shortening that caused a further northward migration of the Apenninic frontal thrust (Faulting Stage D of Festa et al., 2005; see also Artoni et al., 2010;Festa, 2011;Mosca et al., 2010). Finally, the Nstriking Schizzola valley fault, which cuts the SDDZ, probably represents a fault system younger than Early Pliocene as suggested by Perotti and Vercesi (1991) and Vercesi et al. (2015).

Software
The geological map and map inclusions were digitized and edited with Adobe Illustrator CC.