ABSTRACT

A novel magnetic Fe₃O₄@chitosan@taurine adsorbent (MCT) was prepared by surface modification of magnetic chitosan nano-composites with taurine-glutaraldehyde solution. The adsorbents were characterized by FTIR, SEM, TEM, XRD, TGA and VSM techniques, respectively. According to the FTIR spectrum of MCT, the characteristic peaks of the SO₃^-group on MCT were observed to have a shift after adsorption of the cationic dye, which indicates that there may be electrostatic attraction between the MCT and the cationic dye. Moreover, the saturation magnetization of MCT was found to be 20.797 emu g^-1, suggesting that MCT has sufficient magnetic response to meet the need of magnetic separation. The adsorption properties of cationic dyes by MCT were further investigated by using methylene blue (MB) as a representative. The adsorption behaviour of MB by MCT was well described by the pseudo-second order kinetic model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of MB calculated from the Langmuir model fitting was 204.1 mg g⁻¹ at pH 5 and 384.6 mg g⁻¹ at pH 9, respectively, and the adsorption equilibrium could be reached within 10 min. Besides, the negative values of ΔG° and ΔH° suggested that the adsorption process was spontaneous and exothermic, and the good reusability indicated that MCT could act as a recyclable adsorbent for dye adsorption. All of these results illustrate that MCT has great potential for practical application in removal of cationic dyes from aqueous solutions.

GRAPHICAL ABSTRACT