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Xenobiotica

the fate of foreign compounds in biological systems
Volume 25, 1995 - Issue 7
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Original Article

Cation radicals of organosulphur compounds

Pages 637-651
Received 12 Nov 1994
Published online: 27 Aug 2009

1. Biological and biomimetic oxidations of thioethers are reviewed.

2. γ-Radiolysis, pulse radiolysis, photochemical, chemical, and electrochemical methods for generating sulphur cation radicals are discussed and exemplified.

3. The major reactions of sulphur cation radicals: nucleophilic attack, electron transfer, decarboxylation, reaction with O2, C-S, C-C, and α-C-M bond cleavages, sulphur abstraction, and rearrangements are presented.

 

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