N‐Nitrosamines and precursors are present in rubber products in which the accelerators and stabilizers used in the vulcanization process were derived from dialkylamines. Research was performed to develop data concerning the presence of N‐nitrosamines and precursors so that the health significance of the exposure problem related to infant ingestion of these chemicals could be properly assessed. Volatile N‐nitrosamines were determined in cut‐up pacifier nipples by extraction with dichloromethane followed by concentration in a Kuderna‐Danish evaporator, high‐temperature mineral oil purge and trap, and analysis by gas chromatography‐thermal energy analysis (GC‐TEA). N‐Nitro‐sodibutylamine (NDBA) was the principal N‐nitrosamine found, with concentrations up to 427 ppb. N‐Nitrosamines and precursors in cut‐up and intact nipples were determined by GC‐TEA after a single extraction with artificial saliva. NDBA was the principal nitrosamine found, at levels up to 1040 ppb, while dibutylamine (DBA) was the principa/precursor found, at levels up to 3390 ppb. The persistence of these compounds in intact nipples was determined by multiple artificial saliva extractions. Amounts of NDBA and DBA found after 15 artificial saliva extractions of intact pacifier nippies totalled 824 ppb and 15.6 ppm, respectively. N‐Nitrosamine levels generally showed a gradual decrease in concentration with each extraction, whereas no consistent trend could be determined for concentrations of precursors.