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Journal of Environmental Science and Health, Part A

Toxic/Hazardous Substances and Environmental Engineering
Volume 44, 2009 - Issue 6
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Extractability and leachability of Pb in a shooting range soil amended with poultry litter ash: Investigations for immobilization potentials

, &
Pages 583-590
Received 27 Oct 2008
Published online: 31 Mar 2009

The use of agricultural and industrial by-products as a metal immobilizing agent is cost effective for remediation of vast amounts of contaminated soil. The objective of this study was to assess the effect of an amendment (poultry litter ash) on immobilizing Pb in a shooting range soil. For a contaminant transport study, the soil admixed with amendment at the rate of 0 (control), 0.5, 1, 3 and 6%(w/w) was packed into soil columns and eluted solutions were collected through 40 pore volumes. The amendment application significantly reduced the concentrations of water-extractable and toxicity characteristic leaching procedure (TCLP)-extractable Pb by > 96% and > 97% of control, respectively. The contaminant transport study demonstrated that increasing amendment additions up to 3% decreased eluted Pb concentration below 0.5 mg L−1. The X-ray diffraction peaks indicative of chloropyromorphite were observed in the soil of the 1 and 3% treatments, but were less intense in the 0.5 and 6% treatments. The 6% treatment had an eluted Pb concentration of 13 mg L−1 at the first pore volume and significantly increased the total Pb elution (38 mg kg−1), mainly due to a drastic increase of organically complexed Pb as a result of soil alkalinization. These results suggest that poultry litter ash may have potential for immobilizing Pb in shooting range sites, if the soil pH is properly managed.

Acknowledgments

The authors would like to express their gratitude to Gary White (Gifu Shotoku Gakuen University, Japan) for his professional editorial assistance on manuscript preparation. We are grateful to Chihiro Yoshimura and Li Fusheng (Gifu University, Japan) for providing the use of TOC analyzer, and to Yutaka Oya (Gifu University, Japan) for providing the use of XRD instrumentation. The chemical analyses, in part, were conducted by using the instruments at the Division of Instrumental Analysis in Gifu University. This study was partially supported by funds, Grant-in-Aid for Scientific Research (B) for T. Sato, and Grant-in-Aid for Young Scientists (B) for Y. Hashimoto provided from The Ministry of Education, Culture, Sports, Science and Technology, Japan.

 

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