Abstract

Water treatment works using coagulation/flocculation in the process stream will generate a waste sludge. This sludge is termed as ferric, alum, or lime sludge based on which coagulant was primarily used. The works in Adana, Turkey uses ferric chloride. The potential for using this sludge for the treatment of vegetable oil refinery industry wastewater by coagulation has been investigated. The sludge acted as a coagulant and excellent oil and grease, COD and TSS removal efficiencies were obtained. The optimum conditions were a pH of 6 and a sludge dose of 1100 mg SS 1^‐1. The efficiency of sludge was also compared with alum and ferric chloride for the vegetable oil refinery wastewater. At doses of 1300–1900 mg SS 1^‐1, the sludge was as effective as ferric chloride and alum at removing oil and grease, COD, and TSS. In addition, various combinations of ferric chloride and waterworks sludge were also examined. Under the condition of 12.5 mg 1^‐1 fresh ferric chloride and 1000 mg SS 1^‐1 sludge dose, 99% oil and grease 99% TSS and 83% COD removal efficiencies were obtained.