Skip to Main Content
 
Translator disclaimer

The phase behaviour of the thermotropic cubic mesogen 1,2-bis(4′-n-hexyloxybenzoyl)hydrazine [BABH(6)] was investigated under pressure up to about 55 MPa using a polarising optical microscope equipped with a high-pressure optical cell. BABH(6) shows the crystal (Cr)–cubic (Cub)–isotropic liquid (I) phase transition at ambient pressure on heating. The smectic C (SmC) phase was induced above 32 MPa, showing the unusual phase sequence of Cr–Cub–SmC–I, similar to those in BABH(n) (n = 8–10). The boundary between the Cub and SmC phases exhibited a negative slope dT/dP of about –1.0 ºC MPa−1.

Funding

This work was partly supported by a Grant-in-Aid for Scientific Research (C) 25410091 from the Japan Society for the Promotion of Science (JSPS); by a Grant-in-Aid for Scientific Research on Priority Areas [446/19022012] from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) (for S.K.); by a Grant-in-Aid for Scientific Research on Priority Areas [463/19031002] from MEXT; and by a Grant-in-Aid for Scientific Research on (B) 22350056 from JSPS (for K.S.).

 

Related articles

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.