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Journal

Molecular Physics

An International Journal at the Interface Between Chemistry and Physics

Volume 80, 1993 - Issue 6

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Pages 1339-1357
Received 12 Nov 1992
Accepted 01 Apr 1993
Published online: 23 Aug 2006
 
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We have evaluated the bulk and surface elastic constants of a nematic liquid crystal composed of Gay-Berne particles, using a generalization of earlier theories by Poniewierski and Stecki, and Lipkin, Rice and Mohanty. The ratios between surface and bulk elastic constants have been plotted as a function of temperature and at nematic-isotropic coexistence. In particular, the sign of the K 13 (splay-bend) constant has been shown to depend sensitively on details of the intermolecular potential. Results have been contrasted with those obtained from a different theory.

 
Molecular Physics Longuet-Higgins Young Author's Prize

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