Farmyard manure (FYM-BC) and poultry manure (PM-BC) derived biochars were applied as adsorbents to remove Cd2+ from water. Results indicated that PM-BC was a more efficient adsorbent than FYM-BC at all experimental conditions. Maximum Cd2+ adsorption was observed at pH 4, temperature 318 K and contact time 1 h, regardless of biochar type. The Langmuir model predicted maximum adsorption capacity of 90.09 mg g−1 for PM-BC. The data fitting to pseudo-second-order model proposed chemisorption of Cd2+ onto biochars. Thermodynamics indicated that adsorption was spontaneous and endothermic. Post-adsorption analysis provided evidences of strong chemical interactions between biochars’ functional groups and Cd2+ ions.
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Adsorption
High-efficiency remediation of cadmium (Cd2+) from aqueous solution using poultry manure– and farmyard manure–derived biochars
Muhammad Idrees Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, Pakistan; Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, P. R. ChinaCorrespondencem.idrees8223@gmail.com
View further author information, Saima Batool Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, PakistanView further author information, Qaiser Hussain Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi Arabia; Department of Soil Science and Soil Water Conservation, PMAS Arid Agriculture University, Rawalpindi, PakistanView further author information, Hidayat Ullah Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, PakistanView further author information, Mohammad Ibrahim Al-Wabel Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi ArabiaView further author information, Mahtab Ahmad Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi ArabiaView further author information & Jie Kong Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, P. R. ChinaCorrespondencekongjie@nwpu.edu.cn
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Muhammad Idrees Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, Pakistan; Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, P. R. ChinaCorrespondencem.idrees8223@gmail.com
View further author information
, Saima Batool Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, PakistanView further author information
, Qaiser Hussain Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi Arabia; Department of Soil Science and Soil Water Conservation, PMAS Arid Agriculture University, Rawalpindi, PakistanView further author information
, Hidayat Ullah Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Khyber Pakhtunkhwa, PakistanView further author information
, Mohammad Ibrahim Al-Wabel Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi ArabiaView further author information
, Mahtab Ahmad Department of Soil Sciences, College of Food & Agricultural Sciences, King Saud University, Riyadh, Saudi ArabiaView further author information
& Jie Kong Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, P. R. ChinaCorrespondencekongjie@nwpu.edu.cnView further author information
show allPages 2307-2317
Received 22 Feb 2016
Accepted 20 Jun 2016
Accepted author version posted online: 01 Jul 2016
Published online: 18 Aug 2016
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