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Adsorption

High-efficiency remediation of cadmium (Cd2+) from aqueous solution using poultry manure– and farmyard manure–derived biochars

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Pages 2307-2317
Received 22 Feb 2016
Accepted 20 Jun 2016
Accepted author version posted online: 01 Jul 2016
Published online: 18 Aug 2016
 
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Farmyard manure (FYM-BC) and poultry manure (PM-BC) derived biochars were applied as adsorbents to remove Cd2+ from water. Results indicated that PM-BC was a more efficient adsorbent than FYM-BC at all experimental conditions. Maximum Cd2+ adsorption was observed at pH 4, temperature 318 K and contact time 1 h, regardless of biochar type. The Langmuir model predicted maximum adsorption capacity of 90.09 mg g−1 for PM-BC. The data fitting to pseudo-second-order model proposed chemisorption of Cd2+ onto biochars. Thermodynamics indicated that adsorption was spontaneous and endothermic. Post-adsorption analysis provided evidences of strong chemical interactions between biochars’ functional groups and Cd2+ ions.

Additional information

Funding

This research is supported by the Fundamental Research Funds for the Central Universities of China (3102015BJ(II)JGZ026).

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